G. Diezemann et H. Sillescu, DIPOLAR INTERACTIONS IN DEUTERON SPIN SYSTEMS .2. TRANSVERSE RELAXATION, The Journal of chemical physics, 103(15), 1995, pp. 6385-6393
The effect of the so-called local field terms of the dipolar interacti
ons on the transverse relaxation of deuteron spin systems is investiga
ted for a variety of physical situations. It is shown that the respons
e of the spin systems to arbitrary pulse sequences can be calculated i
n an operator formalism. For illustration, calculations of the signals
following a quadrupolar echo sequence are performed, and expressions
for the echo amplitude are given including that for a system of a deut
eron coupled to an arbitrary number of spins. A simple model is formul
ated and the transverse relaxation rate in supercooled liquids is calc
ulated for the whole range of motional correlation times of experiment
al interest. (C) 1995 American Institute of Physics.