TRANSFORMATION OF ALDEHYDES INTO (E)-1-ALKENYLBORONIC ESTERS WITH A GEMINAL DICHROMIUM REAGENT DERIVED FROM A DICHLOROMETHYLBORONIC ESTER AND CRCL2

Authors
TAKAI K SHINOMIYA N KAIHARA H YOSHIDA N MORIWAKE T UTIMOTO K
Citation
K. Takai et al., TRANSFORMATION OF ALDEHYDES INTO (E)-1-ALKENYLBORONIC ESTERS WITH A GEMINAL DICHROMIUM REAGENT DERIVED FROM A DICHLOROMETHYLBORONIC ESTER AND CRCL2, Synlett, (9), 1995, pp. 963
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
9
Year of publication
1995
Database
ISI
SICI code
0936-5214(1995):9<963:TOAI(E>2.0.ZU;2-T
Abstract
Synthetically useful (E)-1-alkenylboronic esters are prepared stereose lectively from aldehydes with one-carbon extention by using a geminal dichromium reagent derived from a dichloromethylboronic ester, CrCl2, and LiI under mild conditions.