CRYSTALLIZATION AND STRUCTURE OF HEXAMERIC ACI-9-NITROFLUORENE-POTASSIUM CONTAINING A LIPOPHILICALLY WRAPPED POLYION AGGREGATE [K-6(CIRCLE-PLUS)(O-12)(CIRCLE-MINUS-6)]

Authors
BOCK H DIENELT R SCHODEL H HAVLAS Z
Citation
H. Bock et al., CRYSTALLIZATION AND STRUCTURE OF HEXAMERIC ACI-9-NITROFLUORENE-POTASSIUM CONTAINING A LIPOPHILICALLY WRAPPED POLYION AGGREGATE [K-6(CIRCLE-PLUS)(O-12)(CIRCLE-MINUS-6)], Tetrahedron letters, 36(43), 1995, pp. 7855-7858
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
43
Year of publication
1995
Pages
7855 - 7858
Database
ISI
SICI code
0040-4039(1995)36:43<7855:CASOHA>2.0.ZU;2-7
Abstract
Aci-9-nitrofluorene potassium salt crystallizes as a hexamer around a polyion aggregate [K-6(+)(O-12)(6)(-)] which in addition is solvated b y one dioxane and two tetrahydrofuran molecules. The lipophilic skin { C77H72} limits the size of the thermodynamically favorable metal oxide cluster and provides a molecular self-organization principle for the crystallization of analogous compounds.