NONORTHOGONAL TWINNING IN THIN-FILM OXIDE PEROVSKITES

We have observed nonorthogonal twinning in thin him oxide perovskites. This twinning geometry is equivalent to a 60 degrees rotation of the twinned crystallites about the [111] direction in an [001] oriented fi lm. This twinning is not detectable by the standard x-ray tests for fi lm quality (a radial theta-2 theta scan and a phi scan at a chi of 45 degrees). In this study we observe this twinning in films of PbZrxTi1- xO3, BaTiO3, and SrRuO3 grown by sputtering and MOCVD on MgO and SrTiO 3. These twins are observed in films deposited on a substrate with whi ch there is a large lattice mismatch and in films that are deposited i n an oxygen deficient environment. We propose that these twins result from plastic deformation associated with misfit accommodation and disc uss the twin geometry and the nature of the twin interface. (C) 1995 A merican Institute of Physics.