Near band-gap photoluminescence was observed at low temperatures from
relaxed Si1-xGex layers with 0.17<x<0.32 grown on Si(001) by ultrahigh
vacuum chemical vapor deposition. The luminescence from undoped sampl
es was dominated at low temperature and low excitation densities by re
combination of excitons bound to alloy fluctuations exhibiting the sma
llest full width at half-maximum, 2.44 meV, reported for relaxed epita
xial Si1-xGex layers. Excitons bound to phosphorous and boron were als
o observed as was free exciton recombination. (C) 1995 American Instit
ute of Physics.