A comprehensive chemical-dynamical model is used to investigate the in
teraction of gravity waves with twenty minor species involved in the a
tomic sodium chemistry in the mesopause region. We find that chemistry
becomes important on the underside of the sodium layer, primarily bel
ow 85 km altitude, where the relative importance of chemistry in wave-
driven sodium fluctuations increases with increasing wave period and i
ncreasing horizontal wavelength. We also find that for altitudes below
80 km an adequate determination of the effects of chemistry in these
fluctuations requires the inclusion of several reactions related to oz
one chemistry. However, the atomic Na density is too low this region t
o be routinely observed by current sodium lidars. Importantly, we find
that above 85 km altitude sodium can be treated as a passive tracer o
f gravity wave motions.