EXPERIMENTAL INVESTIGATIONS ON A SODIUM-ION-CONDUCTING POLYMER ELECTROLYTE BASED ON POLY(ETHYLENE OXIDE)COMPLEXED WITH NAPF6

Authors
HASHMI SA CHANDRA S
Citation
Sa. Hashmi et S. Chandra, EXPERIMENTAL INVESTIGATIONS ON A SODIUM-ION-CONDUCTING POLYMER ELECTROLYTE BASED ON POLY(ETHYLENE OXIDE)COMPLEXED WITH NAPF6, Materials science & engineering. B, Solid-state materials for advanced technology, 34(1), 1995, pp. 18-26
Citations number
22
Categorie Soggetti
Material Science","Physics, Condensed Matter
Journal title
Materials science & engineering. B, Solid-state materials for advanced technology → ACNP
ISSN journal
09215107
Volume
34
Issue
1
Year of publication
1995
Pages
18 - 26
Database
ISI
SICI code
0921-5107(1995)34:1<18:EIOASP>2.0.ZU;2-G
Abstract
Poly(ethylene oxide)-NaPF6 polymer electrolytes have been studied by X -ray diffraction, IR, differential thermal analysis, optical microscop y, polarization, and impedance spectroscopic techniques. The material is shown to be an ionic conductor with t(ion) approximate to 0.98, t(N a+) approximate to 0.45 and t(anion) approximate to 0.53. The sigma vs . 1/T curves show apparent Arrhenius behaviour below and above T-m.