The effect on the electronic structure of an InAs monomolecular plane
inserted in bulk GaAs is investigated theoretically. The (InAs)(1)(GaA
s)(n) (001) strained superlattice is studied via ab initio self-consis
tent pseudopotential calculations. Both electrons and holes are locali
zed nearby the inserted InAs monolayer, which therefore acts as a quan
tum well for all the charge carriers. The small thickness of the inser
ted InAs slab is responsible for high confinement energies of the char
ge carriers, and therefore the interband electron-heavy-hole transitio
n energy is close to the energy gap of the bulk GaAs, in agreement wit
h recent experimental data.