DIHYDROOXATHIINO-FUSED UNSYMMETRICAL TETRATHIAFULVALENES

Citation
J. Hellberg et al., DIHYDROOXATHIINO-FUSED UNSYMMETRICAL TETRATHIAFULVALENES, Journal of materials chemistry, 5(10), 1995, pp. 1549-1551
Citations number
14
Categorie Soggetti
Chemistry Physical","Material Science
ISSN journal
09599428
Volume
5
Issue
10
Year of publication
1995
Pages
1549 - 1551
Database
ISI
SICI code
0959-9428(1995)5:10<1549:DUT>2.0.ZU;2-H
Abstract
The synthesis of three new unsymmetrical tetrathiafulvalenes (TTFs), a ll fused with dihydrooxathiino rings, is described. The new donors all showed two reversible cyclic voltammetric halfwaves at values lower o r similar to the value of bis(ethylenedithio)-TTF. The dimethyl deriva tive DMOX-TTF, 5, gave well formed radical cation salts of close to 2: 1 stoichiometry with several anions.