THE M(DDDT)(2) FAMILY OF CONDUCTING COMPLEXES - [NI(DDDT)(2)](3)(AUBR2)(2), THE FIRST QUASI-2-DIMENSIONAL METAL STABLE DOWN TO AT LEAST 1.3K

Authors
KUSHCH LA GRITSENKO VV BURAVOV LI KHOMENKO AG SHILOV GV DYACHENKO OA MERZHANOV VA YAGUBSKII EB ROUSSEAU R CANADELL E
Citation
La. Kushch et al., THE M(DDDT)(2) FAMILY OF CONDUCTING COMPLEXES - [NI(DDDT)(2)](3)(AUBR2)(2), THE FIRST QUASI-2-DIMENSIONAL METAL STABLE DOWN TO AT LEAST 1.3K, Journal of materials chemistry, 5(10), 1995, pp. 1633-1638
Citations number
24
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Journal of materials chemistry → ACNP
ISSN journal
09599428
Volume
5
Issue
10
Year of publication
1995
Pages
1633 - 1638
Database
ISI
SICI code
0959-9428(1995)5:10<1633:TMFOCC>2.0.ZU;2-H
Abstract
The first stable molecular metal, [Ni(dddt(2)](3)(AuBr2)(2), among the M(dddt)(2) family of conducting charge-transfer salts has been prepar ed and its crystal structure has been solved by X-ray analysis. The or igin of the metallic conductivity of [Ni(dddt)(2)](3)(AuBr2)(2) as wel l as the stability of this salt with respect to metal-to-insulator tra nsitions is explained on the basis of tight-binding band structure cal culations.