DOUBLE-ROTATION AND MAGIC-ANGLE-SPINNING NUCLEAR-MAGNETIC-RESONANCE STUDY OF AL-27 - REEXAMINATION OF THE ALUMINUM BORATE 9AL(2)O(3)CENTER-DOT-2B(2)O(3)

Authors
MASSIOT D MULLER D HUBERT T SCHNEIDER M KENTGENS APM COTE B COUTURES JP GESSNER W
Citation
D. Massiot et al., DOUBLE-ROTATION AND MAGIC-ANGLE-SPINNING NUCLEAR-MAGNETIC-RESONANCE STUDY OF AL-27 - REEXAMINATION OF THE ALUMINUM BORATE 9AL(2)O(3)CENTER-DOT-2B(2)O(3), Solid state nuclear magnetic resonance, 5(2), 1995, pp. 175-180
Citations number
16
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical","Physics, Condensed Matter
Journal title
Solid state nuclear magnetic resonance → ACNP
ISSN journal
09262040
Volume
5
Issue
2
Year of publication
1995
Pages
175 - 180
Database
ISI
SICI code
0926-2040(1995)5:2<175:DAMNS>2.0.ZU;2-7
Abstract
Al-27 nuclear magnetic resonance spectra of polycrystalline aluminium berate 9Al(2)O(3) . 2B(2)O(3) have been measured in double rotation at 11.7 and 7.0 T and high-speed magic-angle spinning at 7.0, 9.4, 11.7, 14.1 and 17.6 T. Spinning sidebands from the satellite transitions we re observed at 7.0 and 14.1 T. Each of the four structural aluminium s ites [Al(IV), Al(V)(1), Al(V)(2) and Al(VI)] are observed, characteris ed and assigned in the spectra. The obtained parameter set gives a ful ly consistent interpretation in agreement with the crystal structure o f the compound.