The determination of reliable neutron W values for a dosimetrically im
portant medium such as methane-based tissue-equivalent gas relies on k
nowing the W values of the charged particles produced by the neutron i
nteractions in that medium. Following the recent evaluation of proton
W values in methane-based tissue-equivalent gas by Siebert et al, it w
as thought appropriate to perform a similar re-evaluation for other si
gnificant secondary charged particles, namely He-4, C-12, N-14 and O-1
6. This would allow the calculation of neutron W values with a complet
ely revised set of data. The re-evaluation shows evidence of a 'bump'
in the He-4 W value curve at similar to 200 keV .amu(-1) similar to th
at reported for protons, but not for C-12, N-14 or O-16 ions. It also
highlights the almost complete absence of experimental data above 60 k
eV .amu(-1) for heavy recoils. Determination of neutron W values has s
hown a small increase below similar to 1 MeV, and a small decrease abo
ve similar to 8 MeV, when compared to the values reported by Siebert e
t al. Furthermore, neutron W values have been calculated for energies
up to 60 MeV for the first time.