DIASTEREOSELECTIVE PERFLUOROALKYLATION OF CHIRAL IMIDE ENOLATES WITH PERFLUOROALKYL IODIDES MEDIATED BY TRIETHYLBORANE

Authors
ISEKI K TAKAHASHI M ASADA D NAGAI T KOBAYASHI Y
Citation
K. Iseki et al., DIASTEREOSELECTIVE PERFLUOROALKYLATION OF CHIRAL IMIDE ENOLATES WITH PERFLUOROALKYL IODIDES MEDIATED BY TRIETHYLBORANE, Journal of fluorine chemistry, 74(2), 1995, pp. 269-271
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
74
Issue
2
Year of publication
1995
Pages
269 - 271
Database
ISI
SICI code
0022-1139(1995)74:2<269:DPOCIE>2.0.ZU;2-F
Abstract
The perfluoroalkylation of lithium enolates of chiral N-acyloxazolidin ones with perfluoroalkyl iodides mediated by triethylborane proceeds w ith good diastereomeric excess (55%-93% de).