Jw. Duff et Rd. Sharma, QUASI-CLASSICAL TRAJECTORY STUDY OF THE N(S-4)-]N-2(X (1)SIGMA(+)(G))+O(P-3) REACTION CROSS-SECTION ON THE EXCITED (3)A' NNO SURFACE(NO(X(2)PI)), Chemical physics letters, 265(3-5), 1997, pp. 404-409
Energy-dependent cross sections for the N(S-4) + NO(X(2) Pi) --> N-2(X
(1) Sigma(g)(+)) + O(P-3) reaction are calculated over the 0.1-3 eV re
lative translational energy range using the quasiclassical trajectory
approach on the ground state (3)A '' and excited (3)A' potential energ
y surfaces neglecting spin-orbit coupling. The dependence of the react
ion cross section on the initial NO vibrational energy is also investi
gated. Representative vibrational and rotational distributions of the
resulting N-2 molecule are given. The motivation of this study is the
possibility that the reaction acts as a sink of non-thermal N(S-4) ato
ms in the terrestrial thermosphere.