CRYSTAL-STRUCTURE OF A NEW CHIRAL PD(0) DIPHOSPHINE COMPLEX AND ITS USE IN ENANTIOSELECTIVE ALLYLIC ALKYLATIONS/

Authors
BOLM C KAUFMANN D GESSLER S HARMS K
Citation
C. Bolm et al., CRYSTAL-STRUCTURE OF A NEW CHIRAL PD(0) DIPHOSPHINE COMPLEX AND ITS USE IN ENANTIOSELECTIVE ALLYLIC ALKYLATIONS/, Journal of organometallic chemistry, 502(1-2), 1995, pp. 47-52
Citations number
59
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
502
Issue
1-2
Year of publication
1995
Pages
47 - 52
Database
ISI
SICI code
0022-328X(1995)502:1-2<47:COANCP>2.0.ZU;2-5
Abstract
The crystal structure of the new chiral Pd(0) complex (R,R)-2 bearing two homochiral diphosphine ligands is reported. Its catalytic activity and enantioselectivity in allylic substitution reactions were investi gated and the results compared to those obtained with various in-situ catalyst systems derived from [Pd(allyl)Cl](2) and diphosphine (R)-1.