TRI-(1-CYCLOHEPTA-2,4,6-TRIENYL)PHOSPHANE COMPLEXES OF RHODIUM(I) ANDIRIDIUM(I)

Authors
HERBERHOLD M BAUER K MILIUS W
Citation
M. Herberhold et al., TRI-(1-CYCLOHEPTA-2,4,6-TRIENYL)PHOSPHANE COMPLEXES OF RHODIUM(I) ANDIRIDIUM(I), Journal of organometallic chemistry, 502(1-2), 1995, pp. 1-4
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
502
Issue
1-2
Year of publication
1995
Pages
1 - 4
Database
ISI
SICI code
0022-328X(1995)502:1-2<1:TCORA>2.0.ZU;2-4
Abstract
Highly symmetrical complexes MCl[P(C7H7)(3)] (M=Rh (3a), Ir (3b); poin t symmetry C-3v) have been synthesized which contain tri(1-cyclohepta- 2,4,6-trienyl)phosphane (1) as a tetradentate tripod ligand. According to the X-ray structure analysis of 3a, the metal occupies the center of a trigonal bipyramid with Cl and P in the axial positions and three double bonds forming the equatorial plane. Chloride abstraction from 3a by AgBF4 leads to Rh[P(C7H7)(3)](BF4-)-B-+ (6a).