We show that the dust grains in a weakly ionized molecular cloud under
going ambipolar diffusion will become partially aligned by Gold's mech
anism with their angular momentum vectors oriented preferentially para
llel to the local magnetic field. We present accurate numerical calcul
ations on the efficiency of Gold's mechanism for oblate, spheroidal, c
ore-mantle grains which include the effects of Barnett relaxation, Lar
mor precession, gas-grain collisions, the evaporation of molecules fro
m ice mantles, and paramagnetic or superparamagnetic relaxation. We ca
lculate the polarized far-infrared emission from warm grains in a plas
ma undergoing ambipolar diffusion, on the ad hoc assumption that Gold'
s mechanism is the only process that aligns the grains. Our calculatio
ns include an accurate treatment of the systematic gas-grain drift ind
uced by electromagnetic and gas drag forces as well as the stochastic
drift associated with random fluctuations in the grain charge. For rea
sonable grain shapes and favorable magnetic field geometries, the line
ar polarization attributable to ambipolar diffusion in a typical cloud
core exceeds approximate to 1% wherever the ion-neutral drift speed e
xceeds a few tenths of a kilometer per second. Large polarizations gre
ater than or similar to 10% are also possible under optimal conditions
where the ion-neutral drift speed is much larger than the gas thermal
speed. We show that the maximum efficiency of Gold's mechanism is in
excellent agreement with the largest alignment inferred from far-infra
red polarimetry of molecular clouds.