STERIC EFFECTS ON THE SOLVATION OF PROTONATED DI-TERT-BUTYL KETONE AND PHENYL TERT-BUTYL KETONE

Authors
BAGNO A BOSO RL FERRARI N SCORRANO G
Citation
A. Bagno et al., STERIC EFFECTS ON THE SOLVATION OF PROTONATED DI-TERT-BUTYL KETONE AND PHENYL TERT-BUTYL KETONE, Journal of the Chemical Society, Chemical Communications, (20), 1995, pp. 2053-2054
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
20
Year of publication
1995
Pages
2053 - 2054
Database
ISI
SICI code
0022-4936(1995):20<2053:SEOTSO>2.0.ZU;2-U
Abstract
The anomalously low basicity of two sterically hindered ketones (Bu(2) (t)CO and PhCOBu(t)) stems from steric hindrance to the solvation of t heir protonated forms.