NEW HOMOLEPTIC METAL-CARBONYL CATIONS - THE SYNTHESES, VIBRATIONAL AND C-13 MAS NMR-SPECTRA OF HEXACARBONYL-RUTHENIUM(II) AND HEXACARBONYL-OSMIUM(II) UNDECAFLUORODIANTIMONATE(V), [RU(CO)(6)][SB2F11](2) AND [OS(CO)(6)][SB2F11](2)

Authors
WANG CQ BLEY B BALZERJOLLENBECK G LEWIS AR SIU SC WILLNER H AUBKE F
Citation
Cq. Wang et al., NEW HOMOLEPTIC METAL-CARBONYL CATIONS - THE SYNTHESES, VIBRATIONAL AND C-13 MAS NMR-SPECTRA OF HEXACARBONYL-RUTHENIUM(II) AND HEXACARBONYL-OSMIUM(II) UNDECAFLUORODIANTIMONATE(V), [RU(CO)(6)][SB2F11](2) AND [OS(CO)(6)][SB2F11](2), Journal of the Chemical Society, Chemical Communications, (20), 1995, pp. 2071-2072
Citations number
22
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
20
Year of publication
1995
Pages
2071 - 2072
Database
ISI
SICI code
0022-4936(1995):20<2071:NHMC-T>2.0.ZU;2-F
Abstract
The new homoleptic carbonyl cations [Ru(CO)(6)](2+) and [Os(CO)(6)](2) are obtained as [Sb2F11](-) salts by the reductive carbonylation of M(SO3F)(3) (M = Ru, Os), under very mild conditions (60-90 degrees C, 1 atm CO), in liquid SbF5 in a simple, one-step procedure, and are cha racterized by FT Raman, FTIR and C-13 MAS NMR spectroscopy.