NMR-STUDIES OF THE ELECTRONIC-STRUCTURE OF LOW-SPIN IRON(III) PHOSPHONITE COMPLEXES - UNUSUAL (D(XZR)D(YZ))(4)(D(XY))(1) CONFIGURATION

Authors
GUILLEMOT M SIMONNEAUX G
Citation
M. Guillemot et G. Simonneaux, NMR-STUDIES OF THE ELECTRONIC-STRUCTURE OF LOW-SPIN IRON(III) PHOSPHONITE COMPLEXES - UNUSUAL (D(XZR)D(YZ))(4)(D(XY))(1) CONFIGURATION, Journal of the Chemical Society, Chemical Communications, (20), 1995, pp. 2093-2094
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
20
Year of publication
1995
Pages
2093 - 2094
Database
ISI
SICI code
0022-4936(1995):20<2093:NOTEOL>2.0.ZU;2-9
Abstract
Complexation of dimethylphenylphosphonite to (5,10,15,20-tetraphenylpo rphyrinato)iron(III) yields a low-spin derivative [Fe(tpp){P(OMe)(2)Ph }(2)]ClO4, showing NMR and EPR properties consistent with an iron(III) ion in the unusual ground-state configuration (d(xz),d(yz))(4) (d(xy) )(1).