COLORIMETRIC DETERMINATION OF IRON WITH DIACETONE ALCOHOL - A NEW ANALYTICAL REAGENT

Authors
Citation
Cm. Ashraf et G. Nabi, COLORIMETRIC DETERMINATION OF IRON WITH DIACETONE ALCOHOL - A NEW ANALYTICAL REAGENT, Journal of the Chemical Society of Pakistan, 17(1), 1995, pp. 18-22
Citations number
29
Categorie Soggetti
Chemistry
ISSN journal
02535106
Volume
17
Issue
1
Year of publication
1995
Pages
18 - 22
Database
ISI
SICI code
0253-5106(1995)17:1<18:CDOIWD>2.0.ZU;2-X
Abstract
The potential of diacetone alcohol as a new analytical reagent has bee n investigated for numerous cations. These studies have provided basis cf a new and simple method for the spectrophotometric determination o f Fe(II). The reddish brown coloured complex of Fe(III) with this new reagent at the natural pH (1.33) obeys Beer - Lambert's law over usefu l range of iron concentration (25-150 ppm). The visual Limit of identi fication is 5 parts of ion per million parts of solution. This reagent may also be used to differentiate between ferrous and ferric ions.