SYNTHESIS OF MONOLIGATE DITERTIARY PHOSPHINO COMPLEXES OF NIOBIUM(IV)CHLORIDE AND THEIR BONDING INTERACTION WITH MO(CO)(6)

Authors
SHARMA S",SONIKA,"GUPTA S VERMANI OP NARULA AK
Citation
S. Sharma S",sonika,"gupta et al., SYNTHESIS OF MONOLIGATE DITERTIARY PHOSPHINO COMPLEXES OF NIOBIUM(IV)CHLORIDE AND THEIR BONDING INTERACTION WITH MO(CO)(6), Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 34(11), 1995, pp. 883-887
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical → ACNP
ISSN journal
03764710
Volume
34
Issue
11
Year of publication
1995
Pages
883 - 887
Database
ISI
SICI code
0376-4710(1995)34:11<883:SOMDPC>2.0.ZU;2-M
Abstract
The reduction of niobium chloride with aluminium or zinc in the presen ce of various ditertiary phosphines give biligate complexes of the typ e [N-2,Cl-8(P P over arc)(2)], while sodium amalgam reduction of NbCl5 give monoligate complexes of the type [Nb2Cl8(P P over arc)(4)]. The complex [Nb2Cl8(dppe)(4)] on further treatment with Mo(CO)(6) yielded heteronuclear bimetallic complex [Nb2Cl8(P P over arc)(4)Mo-2(CO)(8)]. The complexes have been characterized by elemental analysis, IR and N MR spectral studies.