EFFECT OF SUBSTITUTION OF MONOESTER BY DIESTER ON TITANIUM-MAGNESIUM CATALYST PROPERTIES IN PROPENE POLYMERIZATION

Authors
TALAPATRA S DUDCHENKO VK BUKATOV GD ZAKHAROV VA OKKEL LC
Citation
S. Talapatra et al., EFFECT OF SUBSTITUTION OF MONOESTER BY DIESTER ON TITANIUM-MAGNESIUM CATALYST PROPERTIES IN PROPENE POLYMERIZATION, Die Angewandte makromolekulare Chemie, 231, 1995, pp. 61-67
Citations number
11
Categorie Soggetti
Polymer Sciences
Journal title
Die Angewandte makromolekulare Chemie → ACNP
ISSN journal
00033146
Volume
231
Year of publication
1995
Pages
61 - 67
Database
ISI
SICI code
0003-3146(1995)231:<61:EOSOMB>2.0.ZU;2-E
Abstract
Titanium-magnesium catalysts (TMC), containing monoester (ethyl benzoa te) as internal donor, can be transferred to the diester TMC by the tr eatment with TiCl4 and dibutyl phthalate. The activity and the stereos pecificity of the transferred TMC in propylene polymerization are clos e to those of TMC prepared directly in the presence of diester. The su rface area and the porous structure of both types of TMC were studied and the correlation with the activity of these catalysts is discussed.