CRYSTAL PHASE, SPECTRAL FEATURES, AND CATALYTIC ACTIVITY OF SULFATE-DOPED ZIRCONIA SYSTEMS

Citation
C. Morterra et al., CRYSTAL PHASE, SPECTRAL FEATURES, AND CATALYTIC ACTIVITY OF SULFATE-DOPED ZIRCONIA SYSTEMS, Journal of catalysis, 157(1), 1995, pp. 109-123
Citations number
26
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
00219517
Volume
157
Issue
1
Year of publication
1995
Pages
109 - 123
Database
ISI
SICI code
0021-9517(1995)157:1<109:CPSFAC>2.0.ZU;2-Q
Abstract
Several sulfate-doped ZrO2 catalysts (s.d.-ZrO2) have been prepared by sulfating, with either sulfuric acid or ammonium sulfate, samples of monoclinic ZrO2, Y2O3-stabilized tetragonal ZrO2, and amorphous Zr hyd roxide, and by calcining the sulfated precursors at T greater than or equal to 673 K. We then examined (by TEM, XRD, FTIR, and catalytic tes ts) the effect of sulfation on ZrO2 crystal phase and morphology, the effect of ZrO2 crystal phase on the spectroscopic features of the surf ace sulfate groups, and the catalytic behaviour of the three families of s.d.-ZrO2 systems in the isomerization of n-butane. It could be con cluded that the sulfated monoclinic ZrO2 phase is catalytically not ve ry active (if at all), the nonstabilized tetragonal ZrO2 phase is unst able to the sulfation process, and the sulfated tetragonal ZrO2 phase is catalytically active, no matter what the preparative route has been , provided that the sulfated system is calcined at T greater than or e qual to 823 K. The latter condition is discussed in terms of the struc tural and spectroscopic features of the surface sulfate layer. (C) 199 5 Academic Press, Inc.