PREPARATION OF CHELATING RESINS SELECTIVE TO BORIC-ACID BY FUNCTIONALIZATION OF MACROPOROUS POLY(GLYCIDYL METHACRYLATE) WITH 2-AMINO-2-HYDROXYMETHYL-1,3-PROPANEDIOL

Citation
H. Maeda et al., PREPARATION OF CHELATING RESINS SELECTIVE TO BORIC-ACID BY FUNCTIONALIZATION OF MACROPOROUS POLY(GLYCIDYL METHACRYLATE) WITH 2-AMINO-2-HYDROXYMETHYL-1,3-PROPANEDIOL, Separation science and technology, 30(18), 1995, pp. 3545-3554
Citations number
10
Categorie Soggetti
Engineering, Chemical","Chemistry Analytical
ISSN journal
01496395
Volume
30
Issue
18
Year of publication
1995
Pages
3545 - 3554
Database
ISI
SICI code
0149-6395(1995)30:18<3545:POCRST>2.0.ZU;2-Z
Abstract
Macroporous chelating resins containing polyol groups (RGB) were prepa red by the reaction of poly(glycidyl methacrylate) beads with 2-amino- 2-hydroxymethyl-1,3-propanediol, and the behavior of the resulting RGB in the uptake of boric acid was studied. The RGB exhibited high affin ity for boric acid in the pH range of 5 to 9 and took up boric acid se lectively from geothermal power waste solutions in which various miner als were contained. The boric acid adsorbed on the RGB was easily elut ed with 1 mol/dm(3) hydrochloric acid.