A CONVENIENT PREPARATION OF ALLYLIC AMINES

Citation
P. Breuilles et al., A CONVENIENT PREPARATION OF ALLYLIC AMINES, Tetrahedron letters, 36(44), 1995, pp. 8011-8014
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
36
Issue
44
Year of publication
1995
Pages
8011 - 8014
Database
ISI
SICI code
0040-4039(1995)36:44<8011:ACPOAA>2.0.ZU;2-V
Abstract
Addition of aldehydes to tile bis-lithio derivative of aminosulfone 1, followed by treatment of the resulting mixture with N,N'-carbonyl dii midazole gave phenylsulfonyloxazinones. Reduction by Na/Hg then afford ed almost pure (E)- allylamines.