METALLOPORPHYRIN-CATALYZED OXIDATION OF ALKANES WITH MOLECULAR-OXYGENIN THE PRESENCE OF ACETALDEHYDE

Authors
MURAHASHI SI NAOTA T KOMIYA N
Citation
Si. Murahashi et al., METALLOPORPHYRIN-CATALYZED OXIDATION OF ALKANES WITH MOLECULAR-OXYGENIN THE PRESENCE OF ACETALDEHYDE, Tetrahedron letters, 36(44), 1995, pp. 8059-8062
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
44
Year of publication
1995
Pages
8059 - 8062
Database
ISI
SICI code
0040-4039(1995)36:44<8059:MOOAWM>2.0.ZU;2-M
Abstract
The aerobic oxidation of alkanes with acetaldehyde in the presence of metalloporphyrins gives the corresponding alcohols and ketones highly efficiently. Extremely high turnover numbers have been obtained for th e oxidations of cyclohexane using cobalt, manganese, and ruthenium por phyrin catalysts bearing meso-pentafluorophenyl groups.