C SE BOND-CLEAVAGE OF FUNCTIONALIZED SELENIDES BY LITHIUM ARENIDES - APPLICATION TO THE GEMINAL DI-ALLYLATION OF THE CARBONYL GROUP OF ALDEHYDES AND KETONES/

Authors
KRIEF A NAZIH A
Citation
A. Krief et A. Nazih, C SE BOND-CLEAVAGE OF FUNCTIONALIZED SELENIDES BY LITHIUM ARENIDES - APPLICATION TO THE GEMINAL DI-ALLYLATION OF THE CARBONYL GROUP OF ALDEHYDES AND KETONES/, Tetrahedron letters, 36(44), 1995, pp. 8115-8118
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
44
Year of publication
1995
Pages
8115 - 8118
Database
ISI
SICI code
0040-4039(1995)36:44<8115:CSBOFS>2.0.ZU;2-5
Abstract
Selenoacetals as well as mixed (O,Se) acetals react with lithium areni des and produce, besides lithium selenolates, alpha-selenoalkyllithium s or alpha-alkoxyalkyllithiums respectively. We Look advantage of thes e reactions as well as of the ones involving the synthesis of alkyllit hiums from selenides to propose an original method for geminal di-ally lation of the carbonyl group of aldehydes and ketones.