ECOTEST DEVICE FOR ESTIMATION OF ENVIRONMENTAL FATE OF CHEMICALS IN THE LABORATORY

Citation
P. Mikkelson et al., ECOTEST DEVICE FOR ESTIMATION OF ENVIRONMENTAL FATE OF CHEMICALS IN THE LABORATORY, Chemosphere, 31(8), 1995, pp. 3857-3871
Citations number
21
Categorie Soggetti
Environmental Sciences
Journal title
ISSN journal
00456535
Volume
31
Issue
8
Year of publication
1995
Pages
3857 - 3871
Database
ISI
SICI code
0045-6535(1995)31:8<3857:EDFEOE>2.0.ZU;2-E
Abstract
A glass vessel device with water volume of 20 L was constructed for fa st testing of the fate of a chemical in freshwater watercourse environ ment. The dynamic system consisted of natural water with throughflow o f 4.5 mL min(-1) and bottom sediment from a clean oligohumic lake in C entral Finland. Duckweed (Lemna sp.) as plant material, lake mussel (A nodonta piscinalis) and crucian carp (Carassius carassius) as test ani mals were included in the test device. Tetrachloroguaiacol (TeCG) was dissolved at start to water to make 2 mu g L(-1) concentration. The sa me concentration of TeCG was maintained in inflow water. After static and dynamic pre-tests, a dynamic four weeks test at 15 degrees C was r un with natural water taken in winter. Then, two dynamic four weeks ex periments in three parallel devices with water taken in summer (15 deg rees C) and in autumn (10 degrees C) were done. Concentration of TeCG in outflow water and its partition between sediment and water came to an equilibrium. Contents in mussel and fish reached no equilibria duri ng the tests. Six chlorophenolic metabolites of TeCG were identified, but most of the TeCG had reacted to nonidentified degradation products . The degradation rate of TeCG was more dependent on the time of year of water sampling than on the test temperature.