The pulping processes of Aracruz Celulose were optimized and the modif
ications allowed a significant improvement in the effluent quality. A
strong col relation between kappa number and effluent characteristics
was observed. Trials with different combinations of four simultaneous
bleaching sequences were carried out using conventional (60% ClO2 in c
hlorination stage), ECF and TCF bleaching. Results showed reductions o
f color, AOX, COD and BOD, indicating that the right bleaching combina
tion could be a tool used to optimize effluent quality.