Chemical etching rates of BPDA/PDA/ODA/BMI polyimide film by an alkali
ne etching solution with the presence of different kinds of etchants w
ere studied by film-thickness measurement and UV absorption spectrosco
py of dispersible etching residue. The etching rate of polyimide film
in alkaline ethylene diamine solution is highest among the etching sol
utions studied in the present experiment. If an external bias voltage
was applied during etching, the etching rate was increased. The effect
s of temperature, solubility of the etchant, and ultrasonic vibration
on etching rate are also discussed. The presence of a radical in the p
rocess of etching reveals that the etching reaction is a type of radic
al chain reaction. (C) 1995 John Wiley & Sons, Inc.