Mv. Kantak et al., EFFECT OF GAS AND LIQUID PROPERTIES ON GAS-PHASE DISPERSION IN BUBBLE-COLUMNS, Chemical engineering journal and the biochemical engineering journal, 59(2), 1995, pp. 91-100
The effect of gas and liquid properties on the gas phase dispersion ha
s been investigated in bubble column reactors. Data were obtained in t
wo 3.0 m tall bubble columns (of diameters 0.15 m and 0.25 m) and by v
arying superficial phase velocities. A novel experimental technique, a
quadrupole mass spectrometer, was used to measure the tracer gas conc
entration. Data analysis was accomplished via a simple axial dispersio
n model with the inclusion of a mass transfer term. Results indicate t
hat an increase in liquid viscosity and decrease in the liquid surface
tension leads to a decrease in the gas phase dispersion. Further, the
gas properties have no influence on the gas phase dispersion so long
as the mass transfer effects are properly accounted for in the model.
A hydrodynamic model has been proposed to predict the gas phase disper
sion in bubble column reactors. The model distinguishes various bubble
fractions present in the column based on the differences in their ris
e velocities. The model assumes a bimodal distribution of the gas phas
e, i.e. fast-rising bubbles following a plug-flow behavior and slow-ri
sing bubbles which are being entrained and partially backmixed in the
liquid phase. The model has been validated by predicting experimental
as well as literature data on gas phase dispersion under various opera
ting conditions. The proposed model is easy to use since it requires f
ew easily obtainable parameters for the prediction of gas phase disper
sion, which is an essential parameter in the design and upscaling of b
ubble column reactors.