Ij. Shon et Za. Munir, SYNTHESIS OF MOSI2-XNB AND MOSI2-YZRO(2) COMPOSITES BY THE FIELD-ACTIVATED COMBUSTION METHOD, Materials science & engineering. A, Structural materials: properties, microstructure and processing, 202(1-2), 1995, pp. 256-261
The effect of an electric of field on the combustion synthesis of MoSi
2-xNb (0 less than or equal to x less than or equal to 0.45) and MoSi2
-yZrO(2) (0 less than or equal to y less than or equal to 0.15) was in
vestigated. The velocity of the combustion wave in both composite syst
ems increased nearly linearly with an increase in the applied field. C
omposites with x greater than or equal to 0.45 and y greater than or e
qual to 0.15 can only be synthesized in the presence of a field. Altho
ugh, in the absence of a field, the system with x = 0.45 and y = 0.15
can sustain a non-steady combustion wave, the reaction is not complete
and only partial conversion to MoSi2 is evident. For the synthesis of
pure MoSi2, the field was shown to affect the particle size of the pr
oduct. The average particle size decreased when the synthesis was carr
ied out under the effect of the field.