REGIOSELECTIVE AND STEREOSELECTIVE PREPARATION OF 3-TRIMETHYLSILYLALLYLIC ALCOHOLS BY SOLVOLYSIS OF 5-TRIMETHYLSILYLIC DERIVATIVES OF 1-BROMOCYCLOPROPANES AND 1,1-DIBROMOCYCLOPROPANES IN THE PRESENCE OF CUSO4

Authors
KORNEVA OS MENCHIKOV LG KOLTUN ES NEFEDOV OM
Citation
Os. Korneva et al., REGIOSELECTIVE AND STEREOSELECTIVE PREPARATION OF 3-TRIMETHYLSILYLALLYLIC ALCOHOLS BY SOLVOLYSIS OF 5-TRIMETHYLSILYLIC DERIVATIVES OF 1-BROMOCYCLOPROPANES AND 1,1-DIBROMOCYCLOPROPANES IN THE PRESENCE OF CUSO4, Mendeleev communications, (4), 1995, pp. 135-135
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
4
Year of publication
1995
Pages
135 - 135
Database
ISI
SICI code
0959-9436(1995):4<135:RASPO3>2.0.ZU;2-T
Abstract
The interaction of 1-bromo- and 1,1-dibromocyclopropanes with an equim olar quantity of CuSO4 in a DMSO-water mixture (molar ratio halocyclop ropane:CuSO4 . 5H(2)O:DMSO:H2O = 1:1:10-12:14-16) proceeds via cleavag e of the three-membered ring to selectively give the most thermodynami cally stable isomers of the corresponding 3-trimethylsilyl-substituted allylic or 2-bromoallylic alcohols.