TUNNELING IN THE OXIDATIVE ADDITION-REACTION OF METHANE TO A BARE PALLADIUM ATOM

Authors
MAMAEV VM GLORIOZOV IP ISHCHENKO SY SIMONYAN VV MYSHAKIN EM PRISYAJNYUK AV USTYNYUK YA
Citation
Vm. Mamaev et al., TUNNELING IN THE OXIDATIVE ADDITION-REACTION OF METHANE TO A BARE PALLADIUM ATOM, Mendeleev communications, (4), 1995, pp. 137-138
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
4
Year of publication
1995
Pages
137 - 138
Database
ISI
SICI code
0959-9436(1995):4<137:TITOAO>2.0.ZU;2-S
Abstract
Quantum rate constant evaluations and kinetic isotope effects for the oxidative addition of CH4 (and CD4) to a bare Pd atom, calculated in t erms of the Reaction Path Hamiltonian approximation, show quantum tunn eling to play a very important role in the process when T < 200 K.