Ez. Kurmaev et al., X-RAY-EMISSION, PHOTOELECTRON-SPECTRA, AND ELECTRONIC-STRUCTURE OF SR2CUO2F2+DELTA, Physical review. B, Condensed matter, 52(4), 1995, pp. 2390-2394
The electronic structure of the high-T-c superconductor Sr2CuO2F2+delt
a has been investigated by means of x-ray-emission spectroscopy(O K-al
pha, Cu L(alpha,beta), F K-alpha), x-ray-photoelectron spectroscopy, a
nd band-structure calculations using the full-potential linear muffin-
tin orbital method. The local environment of the F atoms and the valen
ce state of the Cu atoms in Sr2CuO2F2+delta are discussed. On the basi
s of the x-ray-photoelectron and x-ray-emission spectra it is conclude
d that the F atoms preferentially bond to Sr atoms in this compound.