REACTION OF 1,2-O-ISOPROPYLIDENE-ALPHA-D-XYLOFURANURONONITRILE WITH PHENYLMAGNESIUM BROMIDE

Authors
KOOS M STEINER B ALFOLDI J
Citation
M. Koos et al., REACTION OF 1,2-O-ISOPROPYLIDENE-ALPHA-D-XYLOFURANURONONITRILE WITH PHENYLMAGNESIUM BROMIDE, Chemicke zvesti, 48(6), 1994, pp. 426-428
Citations number
29
Categorie Soggetti
Chemistry
Journal title
Chemicke zvesti → ACNP
ISSN journal
03666352
Volume
48
Issue
6
Year of publication
1994
Pages
426 - 428
Database
ISI
SICI code
0366-6352(1994)48:6<426:RO1WP>2.0.ZU;2-5
Abstract
Reaction of 1,2-O-isopropylidene-alpha-D-xylofuranurononitrile with ph enylmagnesium bromide in the mole ratio of 1 : 3 afforded 5 iphenyl-1, 2-O-isopropylidene-alpha-D-xylofuranose. Its structure was proved by s pecial NMR techniques. The imine expected from the addition reaction o f Grignard reagent on the nitrile group was not isolated.