Yn. Vodyanitskiy et Aa. Vasilyev, EFFECT OF SURFACE GLEYING ON IRON COMPOUNDS IN SOD-PODZOLIC SOILS ON PERMIAN DEPOSITS, Eurasian soil science, 27(3), 1995, pp. 53-69
Brinckman's ferrolysis theory (1970) is supplemented with the idea of
autoretardation of iron oxide synthesis. This phenomenon results from
changes in the pH and Eh during one of the stages of ferrolysis, which
retard the synthesis of some iron oxides, especially lepidocrocite. A
s a result, ferruginous concretions contain a smaller fraction of lepi
docrocite than does the fine earth. In soils on Permian red deposits,
the lepidocrocite crystals are smaller in size, especially in concreti
ons. Indices such as the bogging index (Fe/Mn) and the Schwertmann cri
terion Fe-o/d do not accurately indicate the degree of gleying in thes
e soils.