Calculations with data for asteroidal cores indicate that Earth's oute
r core may have a rhenium/osmium ratio at least 20 percent greater tha
n that of the chondritic upper mantle, potentially leading to an outer
core with an osmium-187/osmium-188 ratio at least 8 percent greater t
han that of chondrites. Because of the much greater abundance of osmiu
m in the outer core relative to the mantle, even a small addition of m
etal to a plume ascending from the D '' layer would transfer the enric
hed isotopic signature to the mixture. Sources of certain plume-derive
d systems seem to have osmium-187/osmium-188 ratios 5 to 20 percent gr
eater than that for chondrites, consistent with the ascent of a plume
from the core-mantle boundary.