INELASTIC PROCESSES AND INTERACTION ANISOTROPY FOR H- COLLISIONS WITHH-2

Citation
Fa. Gianturco et S. Kumar, INELASTIC PROCESSES AND INTERACTION ANISOTROPY FOR H- COLLISIONS WITHH-2, Journal of physical chemistry, 99(42), 1995, pp. 15342-15347
Citations number
22
Categorie Soggetti
Chemistry Physical
ISSN journal
00223654
Volume
99
Issue
42
Year of publication
1995
Pages
15342 - 15347
Database
ISI
SICI code
0022-3654(1995)99:42<15342:IPAIAF>2.0.ZU;2-D
Abstract
Vibrationally inelastic processes which can occur in collisions of low -energy simple negative ions with diatomic molecules are studied by us ing the H--H-2 system and by applying to it the quantum treatment of t he relevant multichannel scattering theory. The unusual behavior of th e vibrationally inelastic cross sections, integral and differential, i s linked to specific features of the lowest-lying potential-energy sur face, and microscopic effects of such features on the dynamics are dis cussed in relation to what was found earlier for the H+-H-2 system.