J. Kohno et al., ION-MOLECULE REACTION BETWEEN A PROTONATED PHENYL KETONE AND AN ALCOHOL FOLLOWING MULTIPHOTON EXCITATION IN A LIQUID BEAM, Journal of physical chemistry, 99(42), 1995, pp. 15627-15632
An alcohol solution of phenyl ketone C(6)H(5)COR(1), where R(1) is CH3
, C2H5, H, Or C6H5, was introduced into a vacuum as a continuous liqui
d flow (liquid beam) and irradiated with a laser beam at wavelengths o
f 250, 280, and 355 nm. Ions produced by multiphoton ionization in the
liquid beam and ejected from it were analyzed by time-of-flight mass
spectrometry. The mass spectra of the ions produced from various alcoh
ol solutions of phenyl ketones at different excitation wavelengths ind
icate that a protonated phenyl ketone ion, C6H5C(OH)R(I)(+), produced
by laser irradiation reacts with an alcohol molecule, R(2)OH, in the s
olution and C6H5C(OR(2))R(I)(+) is produced. This reaction corresponds
to the initial process for acetal formation from a phenyl ketone and
an alcohol, and these product ions are identified to be its reaction i
ntermediates. When an alcohol solution of benzophenone, C6H5COC6H5, wa
s used, a pinacol ion, (C6H5)(2)C(OH)C(OH)(C6H5)(2)(+) was produced in
addition to C6H5C(OR(2))C6H5+. The appearance of the pinacol ion sugg
ests the presence of benzophenone dimers in the vicinity of the liquid
surface.