M. Zharnikov et al., SPIN-RESOLVED PHOTOEMISSION AND BAND-MAPPING IN EPITAXIAL FCC FE-CO ALLOYS ON CU(100), Journal of magnetism and magnetic materials, 165(1-3), 1997, pp. 250-253
The electronic properties of fee Fe-Co/Cu(100) were investigated by sp
in-resolved photoelectron spectroscopy. At a fixed concentration a dis
persion of the majority and minority bands with Delta(5)-symmetry towa
rds higher binding energy along the Delta-axis of the Brillouin zone c
ould be followed upon increasing photon energy, Upon variation of the
concentration the spectra for the alloy films reveal a gradual shift o
f the Delta(5) minority spin band through the Fermi level and a change
of the sign of the spin polarization at the Fermi level in full agree
ment with the expected tendency from Co to Fe. Such a behavior agrees
with both a simple mixture of the Fe and Co electronic properties in a
randomly mixed alloy film, and a chemical separation (clustering) of
both constituents.