EFFICIENT INTERCHAIN PHOTOLUMINESCENCE IN A HIGH-ELECTRON-AFFINITY CONJUGATED POLYMER

Citation
Idw. Samuel et al., EFFICIENT INTERCHAIN PHOTOLUMINESCENCE IN A HIGH-ELECTRON-AFFINITY CONJUGATED POLYMER, Physical review. B, Condensed matter, 52(16), 1995, pp. 11573-11576
Citations number
27
Categorie Soggetti
Physics, Condensed Matter
ISSN journal
01631829
Volume
52
Issue
16
Year of publication
1995
Pages
11573 - 11576
Database
ISI
SICI code
0163-1829(1995)52:16<11573:EIPIAH>2.0.ZU;2-H
Abstract
We report measurements of photoluminescence efficiency and time depend ence in a high-electron-affinity cyano-substituted derivative of poly( p-phenylenevinylene). We find that the luminescence is much longer liv ed in solid films than in solutions and interpret this result as emiss ion in the film being from an interchain excitation. These results sug gest that intermolecular interactions are an important consideration i n the design of highly luminescent conjugated polymers.