Idw. Samuel et al., EFFICIENT INTERCHAIN PHOTOLUMINESCENCE IN A HIGH-ELECTRON-AFFINITY CONJUGATED POLYMER, Physical review. B, Condensed matter, 52(16), 1995, pp. 11573-11576
We report measurements of photoluminescence efficiency and time depend
ence in a high-electron-affinity cyano-substituted derivative of poly(
p-phenylenevinylene). We find that the luminescence is much longer liv
ed in solid films than in solutions and interpret this result as emiss
ion in the film being from an interchain excitation. These results sug
gest that intermolecular interactions are an important consideration i
n the design of highly luminescent conjugated polymers.