D-F METAL-ION INTERACTION THROUGH FE-C N-LN BRIDGE BETWEEN DICYANOBIS(1,10-PHENANTHROLINE)IRON(II) COMPLEX AND LNCL(3)

Authors
HARADA K YUZURIHARA J ISHII Y SATO N KAMBAYASHI H FUKUDA Y
Citation
K. Harada et al., D-F METAL-ION INTERACTION THROUGH FE-C N-LN BRIDGE BETWEEN DICYANOBIS(1,10-PHENANTHROLINE)IRON(II) COMPLEX AND LNCL(3), Chemistry Letters, (10), 1995, pp. 887-888
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
10
Year of publication
1995
Pages
887 - 888
Database
ISI
SICI code
0366-7022(1995):10<887:DMITFN>2.0.ZU;2-2
Abstract
By adding lanthanoid ion (Ln) to a solution of non-charged iron(II) co mplex, [Fe(CN)(2)(phen)(2)], the blue shift in MLCT band of the Fe(II) complex was observed in ethanol, but was not in DMSO, The extent of t he band shift depends on the lanthanoid ion size, which is explained b y means of Fe-C=N-Ln interaction. In DMSO, however, the lanthanoid ion is solvated too strongly to form the Fe-C=N-Ln bridging. The existenc e of the bridging mode was confirmed by means of the crystal analysis for a Fe2Yb2 tetranuclear complex.