STEREOSELECTIVE CYCLOPOLYMERIZATION OF 1,5-HEXADIENE USING NOVEL BIS(FERROCENYL)ZIRCONOCENE CATALYST

Authors
MITANI M OOUCHI K HAYAKAWA M YAMADA T MUKAIYAMA T
Citation
M. Mitani et al., STEREOSELECTIVE CYCLOPOLYMERIZATION OF 1,5-HEXADIENE USING NOVEL BIS(FERROCENYL)ZIRCONOCENE CATALYST, Chemistry Letters, (10), 1995, pp. 905-906
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
10
Year of publication
1995
Pages
905 - 906
Database
ISI
SICI code
0366-7022(1995):10<905:SCO1UN>2.0.ZU;2-V
Abstract
A novel heterotrinuclear zirconium-iron complex 1 was synthesized and crystal structure of 1 was determined by X-ray diffraction method, The complex 1 efficiently catalyzed cyclopolymerization of 1,5-hexadiene in the coexistence of methylaluminoxane to afford trans-poly(methylene -1,3-cyclopentane) with high stereoselectivity (98% trans).