T. Minowa et al., HYDROGEN-PRODUCTION FROM WET CELLULOSE BY LOW-TEMPERATURE GASIFICATION USING A REDUCED NICKEL-CATALYST, Chemistry Letters, (10), 1995, pp. 937-938
Wet cellulose was gasified at 350 degrees C for 1 h in the presence of
a reduced nickel catalyst under various operating pressures (8-18 MPa
). Hydrogen was obtained specifically at high operating pressures of 1
7-18 MPa. Under the operating pressure of 18 MPa, the gas yield increa
sed with catalyst loading and reached 91 wt% at the catalyst loading o
f 20 wt%. The gas consisted of hydrogen of 50 vol%, carbon dioxide of
40 vol% and methane of 10 vol%, which was equivalent to that the hydro
gen of 70% in the cellulose was recovered as hydrogen gas.