A mathematical model was developed for spray pyrolysis to produce holl
ow spherical ceramic particles. The mechanism was established based on
the previous experimental results. The transfer of mass, momentum, an
d heat inside and around the aerosol droplets was considered simultane
ously. Simulation was carried out to study the effects of operating pa
rameters on the quality of derived particles. The simulated and experi
mental results were in agreement and showed that: (a) raising the pyro
lysis temperature increased the size and size distribution of resultan
t particles, and decreased the specific surface area and the bulk dens
ity; (b) lowering the concentration of starting solution decreased the
size and size distribution of resultant particles, and increased the
specific surface area and bulk density.