The characterization of KEVLAR-29 fibers has been performed by studyin
g their interactions with three model compounds in gaseous form. Water
, aniline, and epoxystyrene were used for this purpose. The effects on
the nature of these interactions of two types of surface engineering,
namely the coating with an epoxy resin and a reactive plasma treatmen
t, were also studied. The results obtained from the three analytical t
echniques used in this work provide a more fundamental understanding o
f the fiber bulk properties vs. their surface characteristics. The dif
fusion, condensation, plasticization, and adsorption mechanisms involv
ed during the interactions between the probes and the KEVLAR fibers ar
e evidenced and discussed. (C) 1995 John Wiley & Sons, Inc.