SYNTHESIS AND CHARACTERIZATION OF [PPH(4)][M(DIOD)(2)], M=NI, PD, CU OR AU - CRYSTAL-STRUCTURE OF [PPH(4)][CU(DIOD)(2)]

Authors
CLEARY CF ROBERTSON N TAKAHASHI M UNDERHILL AE HIBBS DE HURSTHOUSE MB MALIK KMA
Citation
Cf. Cleary et al., SYNTHESIS AND CHARACTERIZATION OF [PPH(4)][M(DIOD)(2)], M=NI, PD, CU OR AU - CRYSTAL-STRUCTURE OF [PPH(4)][CU(DIOD)(2)], Polyhedron, 16(7), 1997, pp. 1111-1117
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
7
Year of publication
1997
Pages
1111 - 1117
Database
ISI
SICI code
0277-5387(1997)16:7<1111:SACO[M>2.0.ZU;2-L
Abstract
The complexes [P(C6H5)(4)][M(diod)(2)][where M = Ni, Pd, Cu or Au (2a, b, c, d)] have been prepared and characterized spectroscopically, ele ctrochemically and by X-ray structure determination for 2c. Preparatio n of 2d involved isolation of an intermediate complex with only one di ed ligand. The Ni complex 2a forms semiconducting charge transfer comp lexes with TTF and BEDT-TTF. Copyright (C) 1997 Elsevier Science Ltd.