CRYSTAL AND MOLECULAR-STRUCTURE OF BROMO(PI-ALLYL)CYTIDINE PALLADIUM(II)

Authors
KHAN BT MOHAN KM KHAN SRA VENKATASUBRAMANIAN K SATYANARYANA T
Citation
Bt. Khan et al., CRYSTAL AND MOLECULAR-STRUCTURE OF BROMO(PI-ALLYL)CYTIDINE PALLADIUM(II), Polyhedron, 15(1), 1996, pp. 63-67
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
1
Year of publication
1996
Pages
63 - 67
Database
ISI
SICI code
0277-5387(1996)15:1<63:CAMOBP>2.0.ZU;2-G
Abstract
The crystal and molecular structure of bromo(pi-allyl)cytidine palladi um(II) has been determined by X-ray diffraction analysis. In this comp lex, cytidine coordinates to palladium(II) through N-3. The pi-allyl m oiety is coordinated as an eta(3)-ligand. The sugar fragment occurs as an envelope in the gauche-gauche conformation. The structure is suppo rted by a network of hydrogen bonds.